Chapter 10 Spectrometric Identification of Organic Compounds Speaker Luo Yiming, Xian Haoyue

Unit 3 test

1、单选题:
​Which of the following compounds has the highest reaction rate by the Sn1 reation?‎​‎
选项:
A: 1-bromobutane
B: 2-bromobutane
C: 2-bromo-2-methylpropane
D: 1-bromo-2-methylpropane
答案: 【 2-bromo-2-methylpropane

2、单选题:
‎Which of the following compounds is the most acidic?‏‎‏
选项:
A: phenol
B: p-cresol
C: p-nitrophenol
D: benzyl alcohol
答案: 【 p-nitrophenol

3、单选题:
​To distinguish phenol from benzyl alcohol, which is not the reagent of choice?‎​‎
选项:
A: FeCl3(aq.)
B: Br2(aq.)
C: NaOH(aq.)
D: NaHCO3(aq.)
答案: 【 NaHCO3(aq.)

4、单选题:
​Which of the following chemical reactions is not true?‏
选项:
A:


B:
C:
D:
答案: 【 

5、单选题:
‌Which of the following groups has the largest chemical shift δ value of protons in 1H NMR spectroscopy?​‌​
选项:
A: -COOH
B: -CHO
C: -OH
D: -CH3
答案: 【 -COOH

6、判断题:
‏Benzyl bromide is more prone to nucleophilic substitution than bromobenzene.‌‏‌
选项:
A: 正确
B: 错误
答案: 【 正确

7、判断题:
‍Phenols are more acidic than alcohols and are more prone to electrophilic substitution than benzene.‍‍‍
选项:
A: 正确
B: 错误
答案: 【 正确

8、判断题:
‌The ratio of the absorption peak area of each group proton in the 1H NMR spectrum is the corresponding ratio of the number of protons.‌‌‌
选项:
A: 正确
B: 错误
答案: 【 正确

9、判断题:
‌Infrared (IR) spectroscopy can provide evidence of the functional groups present in organic molecules. ‎‌‎
选项:
A: 正确
B: 错误
答案: 【 正确

10、判断题:
‌Tert-butyl bromide in NaOH aqueous solution is prone to nucleophilic substitution reaction, resulting in racemic products. ​
选项:
A: 正确
B: 错误
答案: 【 错误

Chapter 13 Derivatives of Carboxylic Acids Speaker Pong Hongjian

Unit 4 test

1、单选题:
‏Which of the following reagents distinguishes benzaldehyde from acetophenone?​‏​
选项:
A: FeCl3(aq.)
B: 2,4-dinitrophenylhydrazine
C: Tollens reagent
D: Fehling reagent
答案: 【 Tollens reagent

2、单选题:
‏Which of the following chemical reactions is true?‎‏‎
选项:
A:
B:
C:
D:
答案: 【 

3、单选题:
​Which of the following substances is in the correct acidic order?‌​(1) CH3CH2CH2COOH  (2) CH3CH(OH)CH2COOH  (3) HOCH2CH2CH2COOH   (4) CH3COCH2COOH‌​‌
选项:
A: (1)>(2)>(3)>(4)
B: (4)>(3)>(1)>(2)
C: (2)>(3)>(4)>(1) 
D: (4)>(2)>(3)>(1)
答案: 【 (4)>(2)>(3)>(1)

4、单选题:
‍Which of the following carboxylic acids is most likely to take place esterification?‏‍‏
选项:
A: CH3CH2COOH
B: CH3CH2CH2COOH
C:  (CH3)2CHCOOH
D:  (CH3)3CCOOH
答案: 【 CH3CH2COOH

5、单选题:
‌Which of the following compounds is most likely to take place ammonolysis?‎‌‎
选项:
A: CH3COOCH3
B:  FCH2COOCH3
C: (CH3)2CHCOOCH3
D: (CH3)3CCOOCH3
答案: 【  FCH2COOCH3

6、判断题:
​The aldehydes and ketones with α-H can take place both iodoform reaction and hydroxyl aldehyde condensation reaction. ‌​‌
选项:
A: 正确
B: 错误
答案: 【 错误

7、判断题:
‍Aldehydes and ketones have lower boiling points than alcohols of similar molecular weight because alcohols have hydrogen-bond interaction, while aldehydes and ketones do not. ‌‍‌
选项:
A: 正确
B: 错误
答案: 【 正确

8、判断题:
‎β-ketoacids are more prone to decarboxylation than α-ketoacids. ‍‎‍
选项:
A: 正确
B: 错误
答案: 【 正确

9、判断题:
‍All compounds containing carbonyl groups are prone to react with substances such as phenylhydrazine and hydroxylamine. ‌‍‌
选项:
A: 正确
B: 错误
答案: 【&n

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