Absorbance Photometric Analysis

Unit test

1、单选题:
​κ of a absorbing complex is always dependent upon the‍
选项:
A: The stability of the complex
B: The thickness of the complex
C: The wavelength of the electromagnetic radiation
D: The concentration of  the complex
答案: 【 The wavelength of the electromagnetic radiation

2、单选题:
‏The Lambert-Beer’s Law can NOT be represented by​
选项:
A: -lgIt/I0 =κbc
B: lgIt/I0 =κbc
C: lg1/T = κbc
D: A = κbc
答案: 【 lgIt/I0 =κbc

3、单选题:
‌The % T of a certain solution at a certain wavelength in a 1.0 cm cell is 50%. the absorbance of this same solution in a 2.0 cm cell is‏
选项:
A: 0.15
B:  0.30 
C:  0.60 
D:  unknown
答案: 【  0.60 

4、单选题:
‌The Lambert-Beer’s law states that the absorbance is proportional to the concentation of the analyte mesured. Which one of the following conditions must be fulfilled when making a calibration plot for a given analyte species?‍
选项:
A: The wavelength must be fixed.
B: The length of light path through the same cell(cuvet) must be fixed.
C: Both of the conditions stated in A and B must be fulfilled simultaneously.
D: the condition stated in B must be fulfilled, but not A.
答案: 【 The wavelength must be fixed.

Acid-base Equilibrium and Acid-base Titration

Unit test

1、单选题:
‎The pH of 0.10 mol·L-1 NH4Cl solution is about‏‎‏‎(Kb=1.8×10-5)‏
选项:
A: 5
B: 6
C: 7
D: 9
答案: 【 5

2、单选题:
‎Which choice listed below have no influence on the buffer capacity?‏
选项:
A: The concentration of the weak acid.
B: The sum of the concentration of the buffer solution.
C: The ratio of the conjugate base to acid.
D: The pKa of the weak acid.
答案: 【 The pKa of the weak acid.

3、单选题:
‍The buffer range of a buffer solution in which there are the same concentrations of Na2HPO4 and Na3PO4 is about (    ). (pKa1=2.12; pKa2=7.21  pKa3=12.32)‏
选项:
A: 1.12~3.12 
B: 6.21~8.21 
C: 11.32~13.32 
D: all the choice above are wrong.
答案: 【 11.32~13.32 

4、单选题:
‌What is the theoretical range of color change of a weak basic indicator whose Kb is 1.0×10-4 ?‍
选项:
A: pH 4.00~6.00
B: pH 5.00~7.00
C: pH 6.00~8.00
D: pH 7.00~9.00
答案: 【 pH 4.00~6.00

5、单选题:
‍Use 0.1000mol·L-1 HCl to titrate a Na2CO3 solution. the volume consumption of  0.1000mol·L-1 HCl is V1 when indicator is phenolphthalein and the volume consumption of 0.1000mol·L-1 HCl is V2 when indicator is methyl orange. What is the relationship between V1 and V2?‏
选项:
A: V1<V2 
B: V1>V2
C: V1=V2
D: all the choice are possible
答案: 【 V1=V2

6、判断题:
​Greater the Ka,greater the range of titration jump. ‌
选项:
A: 正确
B: 错误
答案: 【 正确

7、判断题:
​The pH of the NH3-NH4Cl buffer solution is more than 7, so it can not resist change in  pH down the addition of small amount of strong acid.‌
选项:
A: 正确
B: 错误
答案: 【 错误

8、判断题:
‌H2O, it is a amphoteric substance  in Bronsted theory‍
选项:
A: 正确
B: 错误
答案: 【 正确

9、判断题:
‎The proton balance equation of NH4H2PO4 aqueous solution is c(H+)+ c(H3PO4)=c(NH3)+2c(PO43-)+c(HPO42-) +c(OH-).‍
选项:
A: 正确
B: 错误
答案: 【 正确

10、判断题:

‍选项:
A: 正确
B: 错误
答案: 【 正确

Coordination Compound and Coordination Titration

Unit test

1、单选题:
​What is the ligand number of Co3+ in [Co(en)(C2O4)2]-‌
选项:
A: 3
B: 4
C: 5
D: 6
答案: 【 3

2、单选题:
​To determine the content of Mg2+ and Ca2+ ions in tap water, in order to keep the pH =10, which buffer system listed below is the best?‌
选项:
A: 0.1mol·L-1 HAc — 0.1mol·L-1  NaAc   (Ka = 1.8×10-5)
B: 0.1mol·L-1 NH3·H2O — 0.1mol·L-1 NH4Cl   (Kb = 1.8×10-5)
C: 0.1mol·L-1 NaH2PO4 — 0.02mol·L-1 Na2HPO4   (Ka = 6.23×10-8)
D: 0.1mol·L-1 H2CO3— 0.02mol·L-1 NaHCO3   (Ka = 4.3×10-7)
答案: 【 0.1mol·L-1 NH3·H2O — 0.1mol·L-1 NH4Cl   (Kb = 1.8×10-5)

3、单选题:
‍In [Co(en)(C2O4)2]-,  the coordination number of Co3+ is ​
选项:
A: 2
B: 3
C: 4
D: 6
答案: 【 6

4、单选题:
​[Ag(NH3)2] + is a linear ion, so the type of hybridization of its central atom Ag+ is‏
选项:
A: sp
B: sp2
C: sp3 
D: dsp2
答案: 【 sp

5、判断题:
‍The three general methods for performing EDTA titrations are direct titration, back titration and displacement method.​
选项:
A: 正确
B: 错误
答案: 【 正确

6、判断题:
​In a coordination compound, its coordination number must be  greater or equal to ligand number.‏
选项:
A: 正确
B: 错误
答案: 【 正确

Introduction to Analytical Chemistry

Unit test

1、单选题:
‏When mass of the solid sample is 0.1~10 mg, it is called‎
选项:
A: Meso analysis
B: micro analysis
C: semimicro analysis 
D: trace analysis
答案: 【 micro analysis

2、单选题:
‍Which of the following is not 4 for the number of significant figures (     )?‌
选项:
A: 0.8056
B: pH=4.000
C: 2.800 ×109
D: 17.36%
答案: 【 pH=4.000

3、单选题:
‏In quantitative analysis, which method listed below can not be use to decrease the system e

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